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0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B 0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B 0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B 0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B 0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B 0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B0B 0B0B0B0B0B0B2D000000F700000314000000000080000000008000008080000000008000800080 0000808000C0C0C000C0DCC000A6CAF000FFFBF000A0A0A40080808000FF00000000FF0000FFFF 00000000FF00FF00FF0000FFFF00FFFFFF00040000003402010004000000F00100000300000000 00}\par {\*\HCS_GRAPHIC_NAME 'EXXONMOBIL'}\par \par -------------------------------------------------------------------------- \par \par \par 642454-60 MOBILGREASE XHP 221\par MATERIAL SAFETY DATA BULLETIN\par -------------------------------------------------------------------------- \par \par -------------------------------------------------------------------------- \par 1. PRODUCT AND COMPANY IDENTIFICATION\par -------------------------------------------------------------------------- \par PRODUCT NAME: MOBILGREASE XHP 221\par SUPPLIER: EXXONMOBIL OIL CORPORATION\par 3225 GALLOWS RD.\par FAIRFAX, VA 22037\par \par 24 - Hour Health and Safety Emergency (call collect): 609-737-4411\par \par 24 - Hour Transportation Emergency:\par CHEMTREC: 800-424-9300 202-483-7616\par LUBES AND FUELS: 281-834-3296\par \par Product and Technical Information:\par Lubricants and Specialties: 800-662-4525 800-443-9966\par Fuels Products: 800-947-9147\par MSDS Fax on Demand: 713-613-3661\par MSDS on Internet: http://www.exxon.com\par http://www.mobil.com\par \par -------------------------------------------------------------------------- \par 2. COMPOSITION/INFORMATION ON INGREDIENTS\par -------------------------------------------------------------------------- \par CHEMICAL NAMES AND SYNONYMS: SEVERE TREAT MIN. OILS & ADDITIVES\par \par GLOBALLY REPORTABLE MSDS INGREDIENTS:\par \par Substance Name Approx. Wt%\par -------------- -----------\par ZINC DIALKYL DITHIOPHOSPHATE 1-5\par (68457-79-4)\par \par \par \par See Section 8 for exposure limits (if applicable).\par \par -------------------------------------------------------------------------- \par 3. HAZARDS IDENTIFICATION\par -------------------------------------------------------------------------- \par Under normal conditions of use, this product is not considered hazardous\par according to regulatory guidelines (See section 15).\par \par EMERGENCY OVERVIEW: Dark Blue Grease. DOT ERG No. : NA\par \par POTENTIAL HEALTH EFFECTS: Under normal conditions of intended use, this\par product does not pose a risk to health. Excessive exposure may\par result in eye, skin or respiratory irritation.\par \par For further health effects/toxicological data, see Section 11.\par \par -------------------------------------------------------------------------- \par 4. FIRST AID MEASURES\par -------------------------------------------------------------------------- \par EYE CONTACT: Flush thoroughly with water. If irritation occurs, call a\par physician.\par SKIN CONTACT: Wash contact areas with soap and water. Remove and clean\par oil soaked clothing daily and wash affected area. INJECTION INJURY\par WARNING: If product is injected into or under the skin, or into any\par part of the body, regardless of the appearance of the wound or its\par size, the individual should be evaluated immediately by a physician\par as a surgical emergency. Even though initial symptoms from high\par pressure injection may be minimal or absent, early surgical\par treatment within the first few hours may significantly reduce the\par ultimate extent of injury.\par INHALATION: Remove from further exposure. If respiratory irritation,\par dizziness, nausea, or unconsciousness occurs, seek immediate medical\par assistance. If breathing has stopped, assist ventilation with\par mechanical device or use mouth-to-mouth resuscitation.\par INGESTION: Not expected to be a problem. Seek medical attention if\par discomfort occurs. Do not induce vomiting.\par \par -------------------------------------------------------------------------- \par 5. FIRE-FIGHTING MEASURES\par -------------------------------------------------------------------------- \par EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog.\par SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use\par water to keep fire exposed containers cool. Water spray may be used\par to flush spills away from exposure. Prevent runoff from fire\par control or dilution from entering streams, sewers, or drinking water\par supply.\par SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters\par must use self-contained breathing apparatus.\par UNUSUAL FIRE AND EXPLOSION HAZARDS: None.\par COMBUSTION PRODUCTS: Fumes, smoke, carbon monoxide, sulfur oxides,\par aldehydes and other decomposition products, in the case of\par incomplete combustion.\par Flash Point C(F): > 204(400) (ESTIMATED FOR OIL, ASTM D-92 (COC)).\par Flammable Limits (approx.% vol.in air) - LEL: NE, UEL: NE\par NFPA HAZARD ID: Health: 0, Flammability: 1, Reactivity: 0\par \par -------------------------------------------------------------------------- \par 6. ACCIDENTAL RELEASE MEASURES\par -------------------------------------------------------------------------- \par NOTIFICATION PROCEDURES: Report spills/releases as required to\par appropriate authorities. U.S. Coast Guard and EPA regulations\par require immediate reporting of spills/releases that could reach any\par waterway including intermittent dry creeks. Report spill/release to\par Coast Guard National Response Center toll free number (800)424-8802.\par In case of accident or road spill notify CHEMTREC (800) 424-9300.\par PROCEDURES IF MATERIAL IS RELEASED OR SPILLED:\par LAND SPILL: Shut off source taking normal safety precautions. Take\par measures to minimize the effects on ground water. Recover by\par pumping or contain spilled material with sand or other suitable\par absorbent and remove mechanically into containers. If necessary,\par dispose of adsorbed residues as directed in Section 13.\par WATER SPILL: Confine the spill immediately with booms. Warn other\par ships in the vicinity. Notify port and other relevant authorities.\par Remove from the surface by skimming or with suitable absorbents. If\par permitted by regulatory authorities the use of suitable dispersants\par should be considered where recommended in local oil spill\par procedures.\par ENVIRONMENTAL PRECAUTIONS: Prevent material from entering sewers, water\par sources or low lying areas; advise the relevant authorities if it\par has, or if it contaminates soil/vegetation.\par PERSONAL PRECAUTIONS: See Section 8\par \par -------------------------------------------------------------------------- \par 7. HANDLING AND STORAGE\par -------------------------------------------------------------------------- \par HANDLING: High pressure injection under the skin may occur due to the\par rupture of pressurized lines. Always seek medical attention. No\par special precautions are necessary beyond normal good hygiene\par practices. See Section 8 for additional personal protection advice\par when handling this product.\par STORAGE: Keep containers closed when not in use. Do not store in open or\par unlabelled containers. Store away from strong oxidizing agents and\par combustible materials. Do not store near heat, sparks, flame or\par strong oxidants.\par SPECIAL PRECAUTIONS: Prevent small spills and leakages to avoid slip\par hazard.\par EMPTY CONTAINER WARNING: Empty containers retain residue (liquid and/or\par vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE,\par SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME,\par SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY\par EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to refill or clean\par container since residue is difficult to remove. Empty drums should\par be completely drained, properly bunged and promptly returned to a\par drum reconditioner. All containers should be disposed of in an\par environmentally safe manner and in accordance with governmental\par regulations.\par \par -------------------------------------------------------------------------- \par 8. EXPOSURE CONTROLS/PERSONAL PROTECTION\par -------------------------------------------------------------------------- \par OCCUPATIONAL EXPOSURE LIMITS:\par \par This product does not contain any components which have recognized\par exposure limits.\par \par VENTILATION: Use adequate ventilation.\par RESPIRATORY PROTECTION: No special requirements under ordinary conditions\par of use and with adequate ventilation.\par EYE PROTECTION: Generally eye contact is unlikely with this type\par material. If eye contact is likely, safety glasses with side\par shields or chemical type goggles should be worn.\par SKIN PROTECTION: If prolonged or repeated skin contact is likely, oil\par impervious gloves should be worn. Good personal hygiene practices\par should always be followed.\par \par -------------------------------------------------------------------------- \par 9. PHYSICAL AND CHEMICAL PROPERTIES\par -------------------------------------------------------------------------- \par Typical physical properties are given below. Consult Product Data Sheet\par for specific details.\par \par APPEARANCE: Grease\par COLOR: Dark Blue\par ODOR: Acrid\par ODOR THRESHOLD-ppm: NE\par pH: NA\par BOILING POINT C(F): > 316(600)\par DROP POINT C(F): NE\par FLASH POINT C(F): > 204(400) (ESTIMATED FOR OIL, ASTM D-92 (COC))\par FLAMMABILITY (solids): NE\par AUTO FLAMMABILITY C(F): NA\par EXPLOSIVE PROPERTIES: NA\par OXIDIZING PROPERTIES: NA\par VAPOR PRESSURE-mmHg 20 C: < 0.1\par VAPOR DENSITY: NE\par EVAPORATION RATE: NE\par RELATIVE DENSITY, 15/4 C: 0.87\par SOLUBILITY IN WATER: Negligible\par PARTITION COEFFICIENT: > 3.5\par VISCOSITY AT 40 C, cSt: > 150.0\par VISCOSITY AT 100 C, cSt: > 16.0\par POUR POINT C(F): NA\par FREEZING POINT C(F): NE\par VOLATILE ORGANIC COMPOUND: NE\par NOTE: MOST PHYSICAL PROPERTIES FOR OIL COMPONENT.\par DMSO EXTRACT, IP-346 (WT.%): <3, for mineral oil only\par NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES\par \par FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE\par \par -------------------------------------------------------------------------- \par 10. STABILITY AND REACTIVITY\par -------------------------------------------------------------------------- \par STABILITY (THERMAL, LIGHT, ETC.): Stable.\par CONDITIONS TO AVOID: Extreme heat and high energy sources of ignition.\par INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers.\par HAZARDOUS DECOMPOSITION PRODUCTS: Product does not decompose at ambient\par temperatures.\par HAZARDOUS POLYMERIZATION: Will not occur.\par \par -------------------------------------------------------------------------- \par 11. TOXICOLOGICAL DATA\par -------------------------------------------------------------------------- \par ---ACUTE TOXICOLOGY---\par ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000\par mg/kg). ---Based on testing of similar products and/or the\par components.\par DERMAL TOXICITY (RABBITS): Practically non-toxic (LD50: greater than\par 2000 mg/kg). ---Based on testing of similar products and/or the\par components.\par INHALATION TOXICITY (RATS): Practically non-toxic (LC50: greater than 5\par mg/l). ---Based on testing of similar products and/or the\par components.\par EYE IRRITATION (RABBITS): Practically non-irritating. (Draize score:\par greater than 6 but 15 or less). ---Based on testing of similar\par products and/or the components.\par SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary\par Irritation Index: greater than 0.5 but less than 3). ---Based on\par testing of similar products and/or the components.\par OTHER ACUTE TOXICITY DATA: Although an acute inhalation study was not\par performed with this product, a variety of mineral oils and synthetic\par base oils, such as those in this product have been tested. These\par samples had virtually no effect other than a nonspecific\par inflammatory response in the lung to the aerosolized mineral oil.\par The presence of additives in other tested formulations (in\par approximately the same amounts as in the present formulation) did\par not alter the observed effects.\par \par ---SUBCHRONIC TOXICOLOGY (SUMMARY)---\par No significant adverse effects were found in studies using repeated\par dermal applications of similar formulations to the skin of\par laboratory animals for 13 weeks at doses significantly higher than\par those expected during normal industrial exposure. The animals were\par evaluated extensively for effects of exposure (hematology, serum\par chemistry, urinalysis, organ weights, microscopic examination of\par tissues etc.).\par \par ---REPRODUCTIVE TOXICOLOGY (SUMMARY)---\par No teratogenic effects would be expected from dermal exposure, based on\par laboratory developmental toxicity studies of major components in\par this formulation and/or materials of similar composition.\par \par ---CHRONIC TOXICOLOGY (SUMMARY)---\par Repeated and/or prolonged exposure may cause irritation to the skin, eyes\par or respiratory tract. For mineral base oils: Base oils in this\par product are severely solvent refined and/or severely hydrotreated.\par Chronic mouse skin painting studies of severely treated oils showed\par no evidence of carcinogenic effects. These results are confirmed on\par a continuing basis using various screening methods such as Modified\par Ames Test, IP-346, and/or other analytical methods. For synthetic\par base oils: The base oils in this product have been tested in the\par Ames assay and other tests of mutagenicity with negative results.\par These base oils are not expected to be carcinogenic with chronic\par dermal exposures.\par \par ---SENSITIZATION (SUMMARY)---\par Not expected to be sensitizing based on tests of this product,\par components, or similar products.\par \par -------------------------------------------------------------------------- \par 12. ECOLOGICAL INFORMATION\par -------------------------------------------------------------------------- \par \par ENVIRONMENTAL FATE AND EFFECTS:\par \par This environmental assessment was conducted using information on the\par individual components as no test data was available for this\par specific formulation.\par \par ECOTOXICITY: The major components in the formulation show no aquatic\par toxicity at 1000 mg/L loading, therefore long-term adverse effects\par in the aquatic environment are not expected.\par \par MOBILITY: Not established.\par \par PERSISTENCE AND DEGRADABILITY: This product is expected to be inherently\par biodegradable, as the principal components have been shown to\par degrade at slow to moderate rates.\par \par BIOACCUMULATIVE POTENTIAL: Not established.\par \par \par -------------------------------------------------------------------------- \par 13. DISPOSAL CONSIDERATIONS\par -------------------------------------------------------------------------- \par WASTE DISPOSAL: Product is suitable for burning in an enclosed,\par controlled burner for fuel value. Such burning may be limited\par pursuant to the Resource Conservation and Recovery Act. In\par addition, the product is suitable for processing by an approved\par recycling facility or can be disposed of at an appropriate\par government waste disposal facility. Use of these methods is subject\par to user compliance with applicable laws and regulations and\par consideration of product characteristics at time of disposal.\par \par RCRA INFORMATION: The unused product, in our opinion, is not\par specifically listed by the EPA as a hazardous waste (40 CFR,\par Part 261D), nor is it formulated to contain materials which\par are listed hazardous wastes. It does not exhibit the hazardous\par characteristics of ignitability, corrosivity, or reactivity. The\par unused product is not formulated with substances covered by the\par Toxicity Characteristic Leaching Procedure (TCLP). However, used\par product may be regulated.\par \par -------------------------------------------------------------------------- \par 14. TRANSPORT INFORMATION\par -------------------------------------------------------------------------- \par USA DOT: NOT REGULATED BY USA DOT.\par \par RID/ADR: NOT REGULATED BY RID/ADR.\par \par IMO: NOT REGULATED BY IMO.\par \par IATA: NOT REGULATED BY IATA.\par \par \par -------------------------------------------------------------------------- \par 15. REGULATORY INFORMATION\par -------------------------------------------------------------------------- \par \par US OSHA HAZARD COMMUNICATION STANDARD: When used for its intended\par purposes, this product is not classified as hazardous in accordance\par with OSHA 29 CFR 1910.1200.\par \par \par EU Labeling: Product is not dangerous as defined by the European Union\par Dangerous Substances/Preparations Directives. EU labeling not\par required.\par \par Governmental Inventory Status: All components comply with TSCA, and\par EINECS/ELINCS.\par \par \par U.S. Superfund Amendments and Reauthorization Act (SARA) Title III:\par This product contains no "EXTREMELY HAZARDOUS SUBSTANCES".\par \par SARA (311/312) REPORTABLE HAZARD CATEGORIES: None.\par \par This product contains the following SARA (313) Toxic Release\par Chemicals:\par \par CHEMICAL NAME CAS NUMBER CONC.\par --------------------------- -------------- -------\par ZINC DIALKYL DITHIOPHOSPHATE 68457-79-4 1.3%\par \par \par \par \par \par \par The following product ingredients are cited on the lists below:\par CHEMICAL NAME CAS NUMBER LIST CITATIONS * \par ------------- ---------- --------------\par NAPHTHALENE (COMPONENT ANALYSIS) 91-20-3 16\par LITHIUM HYDROXIDE (0.06%) 1310-65-2 22\par ZINC (ELEMENTAL ANALYSIS) (0.20%) 7440-66-6 22\par LITHIUM-SOAP THICKENER (5.07%) 7620-77-1 22\par ZINC DINONYLNAPHTHALENE SULFONATE 28016-00-4 22\par (0.40%)\par HYDROGENATED CASTOR OIL, LITHIUM 64754-95-6 22\par SALT (0.31%)\par ZINC DIALKYL DITHIOPHOSPHATE 68457-79-4 18, 20, 21, 22, 24,\par (1.35%) 25\par FATTY ACIDS, C16-22, LITHIUM SALTS 68783-36-8 22\par (0.30%)\par \par --- REGULATORY LISTS SEARCHED ---\par 1=ACGIH ALL 6=IARC 1 11=TSCA 4 16=CA P65 CARC 21=LA RTK\par 2=ACGIH A1 7=IARC 2A 12=TSCA 5a2 17=CA P65 REPRO 22=MI 293\par 3=ACGIH A2 8=IARC 2B 13=TSCA 5e 18=CA RTK 23=MN RTK\par 4=NTP CARC 9=OSHA CARC 14=TSCA 6 19=FL RTK 24=NJ RTK\par 5=NTP SUS 10=OSHA Z 15=TSCA 12b 20=IL RTK 25=PA RTK\par 26=RI RTK\par \par * EPA recently added new chemical substances to its TSCA Section 4 test rules. Please contact the supplier to confirm whether the ingredients in this product currently appear on a TSCA 4 or TSCA 12b list. \par Code key:CARC=Carcinogen; SUS=Suspected Carcinogen; REPRO=Reproductive\par \par -------------------------------------------------------------------------- \par 16. OTHER INFORMATION\par -------------------------------------------------------------------------- \par \par USE: INDUSTRIAL GREASE\par \par \par NOTE: PRODUCTS OF EXXON MOBIL CORPORATION AND ITS AFFILIATED COMPANIES\par ARE NOT FORMULATED TO CONTAIN PCBS.\par \par Health studies have shown that many hydrocarbons pose potential human\par health risks which may vary from person to person. Information provided\par on this MSDS reflects intended use. This product should not be used for\par other applications. In any case, the following advice should be\par considered:\par \par INDUSTRIAL LABEL\par \par Under normal conditions of intended use, this product does not pose a\par risk to health. Excessive exposure may result in eye, skin or\par respiratory irritation. Always observe good hygiene measures. First\par Aid: Wash skin with soap and water. Flush eyes with water. If\par overcome by fumes or vapor, remove to fresh air. If ingested do not\par induce vomiting. If symptoms persist seek medical assistance. Read\par and understand the MSDS before using this product.\par \par \par *************************************************************************\par For Internal Use Only: MHC: 1* 1* 1* 1* 1*, MPPEC: A, TRN: 642454-60,\par ELIS: 405805, CMCS97: 97G104, REQ: FRANCE, SAFE USE: L\par EHS Approval Date: 21AUG2001\par *************************************************************************\par \par \par \pard\keep\keepn Information given herein is offered in good faith as accurate, but\par without guarantee. Conditions of use and suitability of the product for\par particular uses are beyond our control; all risks of use of the product\par are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL\par WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF\par MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE\par USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a\par recommendation for uses which infringe valid patents or as extending\par license under valid patents. Appropriate warnings and safe handling\par procedures should be provided to handlers and users. Alteration of this\par document is strictly prohibited. Except to the extent required by law,\par republication or retransmission of this document, in whole or in part, is\par not permitted. Exxon Mobil Corporation and its affiliated companies\par assume no responsibility for accuracy of information unless the document\par is the most current available from an official ExxonMobil distribution\par system. Exxon Mobil Corporation and its affiliated companies neither\par represent nor warrant that the format, content or product formulas\par contained in this document comply with the laws of any other country\par except the United States of America.\par \par \par \pard Prepared by: ExxonMobil Oil Corporation\par Environmental Health and Safety Department, Clinton, USA\par \par \par \pard }